Nanoscale homochiral C(3)-symmetric mixed-valence manganese cluster complexes with both ferromagnetic and ferroelectric properties.

نویسندگان

  • Cai-Ming Liu
  • Ren-Gen Xiong
  • De-Qing Zhang
  • Dao-Ben Zhu
چکیده

Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of which comprises a 22-nucleus mixed-valence manganese(II/III) supratetrahedral cluster cation and an equilateral-triangle trinuclear manganese(III) cluster anion with C(3) symmetry.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 132 12  شماره 

صفحات  -

تاریخ انتشار 2010